ChemInform Abstract: TfOH‐Catalyzed Reaction of Bispropargyl Alcohols with 1,3‐Dicarbonyl Compounds

ChemInform Abstract: TfOH‐Catalyzed Reaction of Bispropargyl Alcohols with 1,3‐Dicarbonyl Compounds

1,3‐Di‐ and 1,2,3‐trisubstituted benzenes are prepared by TfOH‐promoted selective Csp3‐Csp2 σ‐bond cleavage of 1,3‐dicarbonyl compounds in one‐pot.

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Veröffentlicht in:ChemInform 2016-06, Vol.47 (25), p.no-no
Hauptverfasser: Teng, Qinghu, Mo, Shikun, Pan, Jiankun, Wu, Na, Wang, Hengshan, Pan, Yingming
Format: Artikel
Sprache:eng
Schlagworte:
polyphenyl derivatives
rearrangements
ring closure reactions, annulation reactions
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Zusammenfassung:1,3‐Di‐ and 1,2,3‐trisubstituted benzenes are prepared by TfOH‐promoted selective Csp3‐Csp2 σ‐bond cleavage of 1,3‐dicarbonyl compounds in one‐pot.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201625089