Effect of trace Na additions on the hydrogen absorption kinetics of Mg2Ni

It is demonstrated that Na doping can significantly improve the hydriding performance of Mg 2 Ni under an isobaric-isothermal condition of 2 MPa H 2 and 350 °C. This is achieved via an increase of the interphase grain boundary area and density of dislocations as compared to the Na-free material. Significant enrichment of Na + cations on the alloys’ surface coupled with the catalytic effect of metallic Ni are suggested to increase the hydrogen-metal bonding strength facilitating hydrogen adsorption/dissociation. The mechanisms of hydrogen absorption are discussed based on a nucleation and growth theory. Additionally, by means of in situ synchrotron powder x-ray diffraction, the transition of Mg 2 Ni into the stable Mg 2 NiH 0.3 is observed in real-time.