Titanium Enolate Chemistry at the Beginning of the 21st Century
The aim of the microreview is to summarize the current state of knowledge in the field of titanium enolate chemistry. The authors focus on stereoselective organic syntheses promoted by titanium enolates and analyze developments in the synthetic methodology observed in this area during the last fifte...
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| Veröffentlicht in: | European journal of organic chemistry 2016-03, Vol.2016 (8), p.1476-1493 |
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| container_end_page | 1493 |
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| container_issue | 8 |
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| container_title | European journal of organic chemistry |
| container_volume | 2016 |
| creator | Cież, Dariusz Pałasz, Aleksandra Trzewik, Bartosz |
| description | The aim of the microreview is to summarize the current state of knowledge in the field of titanium enolate chemistry. The authors focus on stereoselective organic syntheses promoted by titanium enolates and analyze developments in the synthetic methodology observed in this area during the last fifteen years.
This microreview covers areas of current applications of titanium(IV) enolates in modern organic synthesis. It focuses on recent developments in the field of titanium(IV)‐mediated aldol, aldol‐like, Mannich, and Michael reactions, radical alkylation, oxidative couplings, and Morita–Baylis–Hillman reactions with special emphasis on the last fifteen years. |
| doi_str_mv | 10.1002/ejoc.201501398 |
| format | Article |
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This microreview covers areas of current applications of titanium(IV) enolates in modern organic synthesis. It focuses on recent developments in the field of titanium(IV)‐mediated aldol, aldol‐like, Mannich, and Michael reactions, radical alkylation, oxidative couplings, and Morita–Baylis–Hillman reactions with special emphasis on the last fifteen years.</description><identifier>ISSN: 1434-193X</identifier><identifier>EISSN: 1099-0690</identifier><identifier>DOI: 10.1002/ejoc.201501398</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Aldol reactions ; Diastereoselectivity ; Enolates ; Oxidative coupling ; Reaction mechanisms ; Titanium</subject><ispartof>European journal of organic chemistry, 2016-03, Vol.2016 (8), p.1476-1493</ispartof><rights>Copyright © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Copyright © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3558-841dc7094406f2c3e621498f7be03386846621001e60f5650ee91bf4c69347483</citedby><cites>FETCH-LOGICAL-c3558-841dc7094406f2c3e621498f7be03386846621001e60f5650ee91bf4c69347483</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejoc.201501398$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejoc.201501398$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Cież, Dariusz</creatorcontrib><creatorcontrib>Pałasz, Aleksandra</creatorcontrib><creatorcontrib>Trzewik, Bartosz</creatorcontrib><title>Titanium Enolate Chemistry at the Beginning of the 21st Century</title><title>European journal of organic chemistry</title><addtitle>Eur. J. Org. Chem</addtitle><description>The aim of the microreview is to summarize the current state of knowledge in the field of titanium enolate chemistry. The authors focus on stereoselective organic syntheses promoted by titanium enolates and analyze developments in the synthetic methodology observed in this area during the last fifteen years.
This microreview covers areas of current applications of titanium(IV) enolates in modern organic synthesis. It focuses on recent developments in the field of titanium(IV)‐mediated aldol, aldol‐like, Mannich, and Michael reactions, radical alkylation, oxidative couplings, and Morita–Baylis–Hillman reactions with special emphasis on the last fifteen years.</description><subject>Aldol reactions</subject><subject>Diastereoselectivity</subject><subject>Enolates</subject><subject>Oxidative coupling</subject><subject>Reaction mechanisms</subject><subject>Titanium</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQRi0EEqWwMkdiTjnHjh1PiEalUCo6UEQ3Kw2XNqVJiu0I8u9JCarYmO706Xt30iPkksKAAgTXuKnSQQA0BMpUdER6FJTyQSg4bnfOuE8VW5ySM2s3AKCEoD1yM89dUuZ14Y3Kaps49OI1Frl1pvES57k1ekNc5WWZlyuvyn6CgFrnxVi62jTn5CRLthYvfmefvNyN5vG9P52NH-LbqZ-yMIz8iNO3VILiHEQWpAxFQLmKMrlEYCwSERdtAkBRQBaKEBAVXWY8FYpxySPWJ1fd3Z2pPmq0Tm-q2pTtS02l5CETisq2NehaqamsNZjpncmLxDSagt5L0ntJ-iCpBVQHfOZbbP5p69FkFv9l_Y5tbeHXgU3MuxaSyVC_Po314vEZgulkqIF9A-C1d1Y</recordid><startdate>201603</startdate><enddate>201603</enddate><creator>Cież, Dariusz</creator><creator>Pałasz, Aleksandra</creator><creator>Trzewik, Bartosz</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201603</creationdate><title>Titanium Enolate Chemistry at the Beginning of the 21st Century</title><author>Cież, Dariusz ; Pałasz, Aleksandra ; Trzewik, Bartosz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3558-841dc7094406f2c3e621498f7be03386846621001e60f5650ee91bf4c69347483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aldol reactions</topic><topic>Diastereoselectivity</topic><topic>Enolates</topic><topic>Oxidative coupling</topic><topic>Reaction mechanisms</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cież, Dariusz</creatorcontrib><creatorcontrib>Pałasz, Aleksandra</creatorcontrib><creatorcontrib>Trzewik, Bartosz</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cież, Dariusz</au><au>Pałasz, Aleksandra</au><au>Trzewik, Bartosz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Titanium Enolate Chemistry at the Beginning of the 21st Century</atitle><jtitle>European journal of organic chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2016-03</date><risdate>2016</risdate><volume>2016</volume><issue>8</issue><spage>1476</spage><epage>1493</epage><pages>1476-1493</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The aim of the microreview is to summarize the current state of knowledge in the field of titanium enolate chemistry. The authors focus on stereoselective organic syntheses promoted by titanium enolates and analyze developments in the synthetic methodology observed in this area during the last fifteen years.
This microreview covers areas of current applications of titanium(IV) enolates in modern organic synthesis. It focuses on recent developments in the field of titanium(IV)‐mediated aldol, aldol‐like, Mannich, and Michael reactions, radical alkylation, oxidative couplings, and Morita–Baylis–Hillman reactions with special emphasis on the last fifteen years.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejoc.201501398</doi><tpages>18</tpages></addata></record> |
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| ispartof | European journal of organic chemistry, 2016-03, Vol.2016 (8), p.1476-1493 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aldol reactions Diastereoselectivity Enolates Oxidative coupling Reaction mechanisms Titanium |
| title | Titanium Enolate Chemistry at the Beginning of the 21st Century |
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