Titanium Enolate Chemistry at the Beginning of the 21st Century

The aim of the microreview is to summarize the current state of knowledge in the field of titanium enolate chemistry. The authors focus on stereoselective organic syntheses promoted by titanium enolates and analyze developments in the synthetic methodology observed in this area during the last fifteen years. This microreview covers areas of current applications of titanium(IV) enolates in modern organic synthesis. It focuses on recent developments in the field of titanium(IV)‐mediated aldol, aldol‐like, Mannich, and Michael reactions, radical alkylation, oxidative couplings, and Morita–Baylis–Hillman reactions with special emphasis on the last fifteen years.