ChemInform Abstract: Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

ChemInform Abstract: Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

The scalable title reaction provides cyclopentanones with an α‐quaternary centre in often very high yields and with very high enantiomeric excesses.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2016-03, Vol.47 (13), p.no-no
Hauptverfasser: Craig, Robert A., Loskot, Steven A., Mohr, Justin T., Behenna, Douglas C., Harned, Andrew M., Stoltz, Brian M.
Format: Artikel
Sprache:eng
Schlagworte:
catalysis, phase‐transfer catalysis
cyclopentane derivatives
decarboxylation
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
indan derivatives
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Beschreibung
Zusammenfassung:The scalable title reaction provides cyclopentanones with an α‐quaternary centre in often very high yields and with very high enantiomeric excesses.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201613091