Synthesis of a Benzenethiol-derivatized Porphyrin for Self-assembly

Synthesis of a Benzenethiol-derivatized Porphyrin for Self-assembly

The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miya...

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Veröffentlicht in:Chinese journal of chemistry 2012-08, Vol.30 (8), p.1841-1844
1. Verfasser: 万继成 孙会谦 黄学斌
Format: Artikel
Sprache:eng
Schlagworte:
porphyrin
self-assembly
thiol
催化剂中毒
催化反应
卟啉
合成
生物保护
自组装
苯硫酚
衍生物
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Zusammenfassung:The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201200345