ChemInform Abstract: Organocatalysis for the Synthesis of Optically Active [beta]-Malonophosphonates

Phospha--Michael addition of P(O--Et)3 to benzylidenemalononitriles (I) in the presence of a proline-based organocatalyst represents one of the most straightforward routes for the synthesis of optically active [beta]-malonophosphonates (III) (13 examples).

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Veröffentlicht in:ChemInform 2014-02, Vol.45 (8)
Hauptverfasser: Thorat, Prashant B, Goswami, Santosh V, Magar, Rupali L, Bhusare, Sudhakar R
Format: Artikel
Sprache:eng
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Zusammenfassung:Phospha--Michael addition of P(O--Et)3 to benzylidenemalononitriles (I) in the presence of a proline-based organocatalyst represents one of the most straightforward routes for the synthesis of optically active [beta]-malonophosphonates (III) (13 examples).
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201408206