(Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber

(Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber

Doing things by half: Palladium nanoparticles supported on the nitrogen‐doped carbon nanofiber (Pd/N‐CNF‐H) are synthesized by thermally decomposing Pd2(dba)3⋅CHCl3 in toluene in the presence of N‐CNF‐H, and act as efficient catalysts for the partial hydrogenation of internal alkynes to the correspo...

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Veröffentlicht in:ChemCatChem 2012-06, Vol.4 (6), p.778-781
Hauptverfasser: Lee, Youngjin, Motoyama, Yukihiro, Tsuji, Keita, Yoon, Seong-Ho, Mochida, Isao, Nagashima, Hideo
Format: Artikel
Sprache:eng
Schlagworte:
alkyne
heterogeneous catalysis
hydrogenation
nanofiber
nitrogen-doped
palladium
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Zusammenfassung:Doing things by half: Palladium nanoparticles supported on the nitrogen‐doped carbon nanofiber (Pd/N‐CNF‐H) are synthesized by thermally decomposing Pd2(dba)3⋅CHCl3 in toluene in the presence of N‐CNF‐H, and act as efficient catalysts for the partial hydrogenation of internal alkynes to the corresponding (Z)‐alkenes in high turnover numbers.
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201200058