ChemInform Abstract: A Novel Allyl Transfer Coupled with a Grob Fragmentation

ChemInform Abstract: A Novel Allyl Transfer Coupled with a Grob Fragmentation

The attempt to remove the Tbs protecting group in antibiotic precursors of type (I) leads to formation of an unexpected aldehyde of type (II).

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Veröffentlicht in:ChemInform 2016-02, Vol.47 (10), p.no-no
Hauptverfasser: Li, Shao‐Gang, Chen, Hui‐Jun, Yang, Yang‐Yang, Wu, Wen‐Ju, Wu, Yikang
Format: Artikel
Sprache:eng
Schlagworte:
aldehydes (acyclic compounds)
aldehydes (benzene compounds)
cleavage reactions, decomposition reactions, pyrolysis
rearrangements
stereochemistry (general, optical resolution)
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Beschreibung
Zusammenfassung:The attempt to remove the Tbs protecting group in antibiotic precursors of type (I) leads to formation of an unexpected aldehyde of type (II).
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201610031