Enolate Stabilization by Anion-[pi] Interactions: Deuterium Exchange in Malonate Dilactones on [pi]-Acidic Surfaces

Enolate Stabilization by Anion-[pi] Interactions: Deuterium Exchange in Malonate Dilactones on [pi]-Acidic Surfaces

Invited for the cover of this issue is the group of Stefan Matile at the University of Geneva. The cover image depicts the crystal structure of a malonate dilactone placed on a chiral π-acidic surface to measure enolate-π interactions during deuterium exchange. Read the full text of the article at 1...

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Veröffentlicht in:Chemistry : a European journal 2016-02, Vol.22 (8), p.2545
Hauptverfasser: Miros, François N, Zhao, Yingjie, Sargsyan, Gevorg, Pupier, Marion, Besnard, Céline, Beuchat, César, Mareda, Jiri, Sakai, Naomi, Matile, Stefan
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Crystal structure
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Beschreibung
Zusammenfassung:Invited for the cover of this issue is the group of Stefan Matile at the University of Geneva. The cover image depicts the crystal structure of a malonate dilactone placed on a chiral π-acidic surface to measure enolate-π interactions during deuterium exchange. Read the full text of the article at 10.1002/chem.201504008.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201504673