ChemInform Abstract: Catalytic Asymmetric Conjugate Addition of [alpha]-Fluoro [beta]-Ketophosphonates to Nitroalkenes in the Presence of Nickel Complexes

ChemInform Abstract: Catalytic Asymmetric Conjugate Addition of [alpha]-Fluoro [beta]-Ketophosphonates to Nitroalkenes in the Presence of Nickel Complexes

The reaction of [alpha]-fluoro [beta]-ketophosphonates (I) with nitroalkenes [(II) or (IV), resp.] affords the corresponding Michael adducts [(III) or (V), resp.] in high yields, high diastereoselectivities and excellent enantioselectivities.

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Veröffentlicht in:ChemInform 2016-01, Vol.47 (6)
Hauptverfasser: Sung, Hyun Ji, Mang, Joo Yang, Kim, Dae Young
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:The reaction of [alpha]-fluoro [beta]-ketophosphonates (I) with nitroalkenes [(II) or (IV), resp.] affords the corresponding Michael adducts [(III) or (V), resp.] in high yields, high diastereoselectivities and excellent enantioselectivities.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201606212