Increasing the Electrolyte Capacity of Alkaline Zn–Air Fuel Cells by Scavenging Zincate with Ca(OH)2

The use of calcium hydroxide for scavenging zincate species is demonstrated to be a highly effective approach for increasing the electrolyte capacity and improving the performance of the zinc–air fuel cell system. A fundamental approach is established in this study to quantify the formation of calcium zincate as the product of scavenging and the amount of water compensation necessary for optimal performance. The good agreement between predicted and experimental results proves the validity of the proposed theoretical approach. By applying the results of theoretical predictions, both the electrolyte capacity and the cell longevity have been increased by more than 40 %. It is also found that, using Ca(OH)2 to scavenge zincate species in concentrated KOH solutions, affects mostly the removal of zincate, rather than ZnO, from the electrolyte, whereas the presence of excess, free, mobile H2O plays a key role in dissolving ZnO and forming zincate. The results obtained in this study demonstrate that the proposed approach can widely and effectively be applied to all zinc–air cell systems during their discharge cycle. Nab‐n‐grab: Ca(OH)2 is an efficient scavenging agent for zincate ions in the Zn–air system. By establishing a theoretical approach and applying it to an actual Zn–air cell, it is demonstrated that the electrolyte discharge capacity and the cell longevity can be increased by 40 %. The cell performance is also improved. In the picture, green represents the zinc content in the tank, whereas violet represents the reduction of zinc content (in %) after the treatment.