Hydrothermal Fluid Sources of the Fengjia Barite-fluorite Deposit in Southeast Sichuan, China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm3. The fluid composition was mainly H2O (>91.33%), followed by CO2, CH4 and traces of C2H6, CO, Ar, and H2S. The dominant cation was Na+ and the dominant anion Cl‐, followed by Ca2+, SO42‐, K+, and Mg2+, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H2O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone. The temperature during mineralization of the fluorite and barite in early ore‐forming stage was higher than calcite in late ore‐forming Stage about the Fengjia barite‐fluorite deposit. The fluid composition was mainly H2O, followed by CO2, CH4 and traces of C2H6, CO, Ar, and H2S. The dominant ion was Na+ and Cl−, followed by Ca2+, SO42−, K+, and Mg2+. The hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water.