ChemInform Abstract: Formaldehyde as Tethering Organocatalyst: Highly Diastereoselective Hydroaminations of Allylic Amines

An efficient approach to 1,2‐diamine motifs via highly diastereoselective intermolecular Cope‐type hydroaminations of allylamines with hydroxylamines is reported.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-12, Vol.47 (2), p.no-no
Hauptverfasser:	Hesp, Colin R., MacDonald, Melissa J., Zahedi, M. Mehdi, Bilodeau, Didier A., Zhao, Shu-Bin, Pesant, Marc, Beauchemin, Andre M.
Format:	Artikel
Sprache:	eng
Schlagworte:	amination amination, N‐alkylation, N‐arylation diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) Editors' Choice enantioselective syntheses (incl. cis/trans-isomerism) hydroxylamine derivatives (acyclic compounds) N-alkylation N-arylation organocatalysis
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Beschreibung
Zusammenfassung:	An efficient approach to 1,2‐diamine motifs via highly diastereoselective intermolecular Cope‐type hydroaminations of allylamines with hydroxylamines is reported.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201602068