Calculating helium atomic excited states in coordinate space

Two coupled Schrödinger equations are used to calculate excited states of atomic helium. Using product state functions for the two-electron state, the shooting method is used to numerically determine the energies of the allowed singlet and triplet levels. The calculations agree well with the data, a...

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Veröffentlicht in:American journal of physics 2015-12, Vol.83 (12), p.1028-1038
Hauptverfasser: Hall, Shane, Siegel, P. B.
Format: Artikel
Sprache:eng
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Zusammenfassung:Two coupled Schrödinger equations are used to calculate excited states of atomic helium. Using product state functions for the two-electron state, the shooting method is used to numerically determine the energies of the allowed singlet and triplet levels. The calculations agree well with the data, and the coordinate-space basis yields Schrödinger equations for helium that are familiar to students who have used similar methods for the hydrogen atom.
ISSN:0002-9505
1943-2909
DOI:10.1119/1.4932549