ChemInform Abstract: Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis

ChemInform Abstract: Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis

The one‐pot dearomatization of pyridines involves the in situ formation of N‐Troc pyridinium chloride salts followed by nucleophilic addition of ketene acetal (III) in the presence of chiral hydrogen donor catalyst (CTR).

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Veröffentlicht in:ChemInform 2015-11, Vol.46 (47), p.no-no
Hauptverfasser: Garcia Mancheno, Olga, Asmus, Soeren, Zurro, Mercedes, Fischer, Theresa
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Sprache:eng
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optical resolution
organocatalysis
pyridine derivatives
stereochemistry (general
stereochemistry (general, optical resolution)
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container_end_page no
container_issue 47
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container_title ChemInform
container_volume 46
creator Garcia Mancheno, Olga
Asmus, Soeren
Zurro, Mercedes
Fischer, Theresa
description The one‐pot dearomatization of pyridines involves the in situ formation of N‐Troc pyridinium chloride salts followed by nucleophilic addition of ketene acetal (III) in the presence of chiral hydrogen donor catalyst (CTR).
doi_str_mv 10.1002/chin.201547161
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source Wiley Online Library Journals Frontfile Complete
subjects optical resolution
organocatalysis
pyridine derivatives
stereochemistry (general
stereochemistry (general, optical resolution)
title ChemInform Abstract: Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis
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