ChemInform Abstract: Domino Nicholas and Pauson-Khand Process Induced by Nitroarene Reduction

The enyne substrate (I) undergoes an unprecedented transformation into product (III) in which a nitroarene reduction step initiates an endocyclic Nicholas reaction followed by an intramolecular Pauson—Khand cyclization.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-11, Vol.46 (46), p.no-no
Hauptverfasser:	Asamizu, Takamichi, Naruse, Risa, Yongxue, Guo, Kaneda, Kyosuke
Format:	Artikel
Sprache:	eng
Schlagworte:	annulation reactions fused pyridine derivatives multi-membered O multi‐membered O,N,S‐heterocycles (with at least 2 different heteroatoms) ring closure reactions ring closure reactions, annulation reactions S-heterocycles (with at least 2 different heteroatoms)
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Beschreibung
Zusammenfassung:	The enyne substrate (I) undergoes an unprecedented transformation into product (III) in which a nitroarene reduction step initiates an endocyclic Nicholas reaction followed by an intramolecular Pauson—Khand cyclization.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201546037