ChemInform Abstract: Nazarov reactions Intercepted by (4 + 3) Cycloadditions with Oxygen-Substituted Dienes

ChemInform Abstract: Nazarov reactions Intercepted by (4 + 3) Cycloadditions with Oxygen-Substituted Dienes

An oxyallyl cation, generated by Nazarov reaction of an allenyl vinyl ketone, is trapped by regioselective cycloaddition with 2‐siloxy‐1,3‐butadienes to give bicyclo[4.2.1]nonane derivatives.

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Veröffentlicht in:ChemInform 2015-10, Vol.46 (43), p.no-no
Hauptverfasser: LeFort, Francois M., Mishra, Vinayak, Dexter, Graham D., Morgan, Timothy D. R., Burnell, D. Jean
Format: Artikel
Sprache:eng
Schlagworte:
bridged compounds (alicyclic compounds)
cycloaddition reactions
intermediates (and their reactions)
Oxygen
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Zusammenfassung:An oxyallyl cation, generated by Nazarov reaction of an allenyl vinyl ketone, is trapped by regioselective cycloaddition with 2‐siloxy‐1,3‐butadienes to give bicyclo[4.2.1]nonane derivatives.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201543077