Synthesis and Characterization of Bis(2-iminopyrrolyl) Iron(II) Complexes by N-H Bond Activation

Synthesis and Characterization of Bis(2-iminopyrrolyl) Iron(II) Complexes by N-H Bond Activation

The reactions of 2‐iminopyrroles 1–3 with Fe(PMe3)4 afforded the N–H activated bis(2‐iminopyrrolyl) iron(II) complexes 4–6. The structures of compounds 4–6 were determined by single‐crystal X‐ray diffraction. The formation mechanism of complexes 4–6 was discussed.

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2015-09, Vol.641 (11), p.1959-1963
Hauptverfasser: Jiao, Guili, Zhu, Gengyu, Zhang, Shumiao, Sun, Hongjian
Format: Artikel
Sprache:eng
Schlagworte:
2-Iminopyrrole
2‐Iminopyrrole
Iron
N–H activation
Trimethylphosphine
Crystals
Diffraction
Iron
N-H activation
Trimethylphosphine
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Zusammenfassung:The reactions of 2‐iminopyrroles 1–3 with Fe(PMe3)4 afforded the N–H activated bis(2‐iminopyrrolyl) iron(II) complexes 4–6. The structures of compounds 4–6 were determined by single‐crystal X‐ray diffraction. The formation mechanism of complexes 4–6 was discussed.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201500157