ChemInform Abstract: Metal-Free Chemoselective ortho-C(sp2)-F Bond Hydroxylation and N-Trifluoroacylation of Fluoroarylamines for Domino Synthesis of 2-(N-Trifluoroacyl)aminophenols

ChemInform Abstract: Metal-Free Chemoselective ortho-C(sp2)-F Bond Hydroxylation and N-Trifluoroacylation of Fluoroarylamines for Domino Synthesis of 2-(N-Trifluoroacyl)aminophenols

A novel method for the selective ortho‐directed monohydroxylation and concomitant N‐trifluoroacylation of 2‐ and 6‐fluoro‐ or 2,6‐difluoro‐substituted anilines is developed.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2015-10, Vol.46 (40), p.no-no
Hauptverfasser: Venkateswarlu, Vunnam, Balgotra, Shilpi, Aravinda Kumar, K. A., Vishwakarma, Ram A., Sawant, Sanghapal D.
Format: Artikel
Sprache:eng
Schlagworte:
aminophenols
cascade reactions
cascade reactions, domino reactions, tandem reactions
chemoselective reactions
domino reactions
hydroxylation
tandem reactions
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Zusammenfassung:A novel method for the selective ortho‐directed monohydroxylation and concomitant N‐trifluoroacylation of 2‐ and 6‐fluoro‐ or 2,6‐difluoro‐substituted anilines is developed.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201540084