ChemInform Abstract: Visible Light Promoted Carbodifluoroalkylation of Allylic Alcohols via Concomitant 1,2-Aryl Migration

The photo‐induced difluoroalkylation of allylic alcohols in the presence of blue LED light affords difluoro 1,5‐dicarbonyl compounds through tandem radical addition and 1,2‐aryl migration.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-08, Vol.46 (34), p.no-no
Hauptverfasser:	Xu, Pan, Hu, Kaidong, Gu, Zhangxi, Cheng, Yixiang, Zhu, Chengjian
Format:	Artikel
Sprache:	eng
Schlagworte:	C-C bond formation catalysis catalysis, phase‐transfer catalysis chemoluminescence halogenated carboxylic acids and esters (acyclic compounds) phase-transfer catalysis photochemistry photochemistry, radiation chemistry, chemoluminescence radiation chemistry radical reactions rearrangements
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The photo‐induced difluoroalkylation of allylic alcohols in the presence of blue LED light affords difluoro 1,5‐dicarbonyl compounds through tandem radical addition and 1,2‐aryl migration.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201534086