Preparation of 2-Arylethynylselanylacetonitriles from 4-Aryl-1,2,3-selenadiazoles

Preparation of 2-Arylethynylselanylacetonitriles from 4-Aryl-1,2,3-selenadiazoles

Base decomposition of 4‐(substituted phenyl)‐1,2,3‐selenadiazoles at room temperature resulted in 2‐(substituted phenyl)‐ethynylselenolate anions, which were immediately reacted with bromoacetonitrile to give a series of 2‐(substituted phenyl)ethynylselanylacetonitriles.

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Veröffentlicht in:Journal of heterocyclic chemistry 2015-07, Vol.52 (4), p.1167-1169
Hauptverfasser: O'Connor, N. A., Sachinvala, N. D., Ganjian, I.
Format: Artikel
Sprache:eng
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Zusammenfassung:Base decomposition of 4‐(substituted phenyl)‐1,2,3‐selenadiazoles at room temperature resulted in 2‐(substituted phenyl)‐ethynylselenolate anions, which were immediately reacted with bromoacetonitrile to give a series of 2‐(substituted phenyl)ethynylselanylacetonitriles.
ISSN:0022-152X
1943-5193
DOI:10.1002/jhet.2216