ChemInform Abstract: Rh(III)-Catalyzed Decarboxylative ortho-Heteroarylation of Aromatic Carboxylic Acids by Using the Carboxylic Acid as a Traceless Directing Group

ChemInform Abstract: Rh(III)-Catalyzed Decarboxylative ortho-Heteroarylation of Aromatic Carboxylic Acids by Using the Carboxylic Acid as a Traceless Directing Group

The highly regioselective title reaction with various heteroarenes (e.g., thiophenes, furans, indoles, indolizines, azoles, and xanthines) uses the carboxylic acid as a traceless directing group.

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Veröffentlicht in:ChemInform 2015-08, Vol.46 (33), p.no-no
Hauptverfasser: Qin, Xurong, Sun, Denan, You, Qiulin, Cheng, Yangyang, Lan, Jingbo, You, Jingsong
Format: Artikel
Sprache:eng
Schlagworte:
Acids
C-C bond formation
decarboxylation
furan derivatives
pyrrole derivatives
regioselective reactions
thiophene derivatives
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Beschreibung
Zusammenfassung:The highly regioselective title reaction with various heteroarenes (e.g., thiophenes, furans, indoles, indolizines, azoles, and xanthines) uses the carboxylic acid as a traceless directing group.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201533068