ChemInform Abstract: Pyrrolidine Catalyzed Reactions of Cyclopentadiene with [alpha],[beta]-Unsaturated Carbonyl Compounds: 1,2- versus 1,4-Additions

ChemInform Abstract: Pyrrolidine Catalyzed Reactions of Cyclopentadiene with [alpha],[beta]-Unsaturated Carbonyl Compounds: 1,2- versus 1,4-Additions

The pyrrolidine-catalyzed reactions of benzalacetones (I) with cyclopentadiene leads to isolable intermediate Michael adducts (III) and (IV), which are converted into 1,2-dihydropentalenes (V) at longer reaction times.

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Veröffentlicht in:ChemInform 2015-08, Vol.46 (33)
Hauptverfasser: Coskun, Necdet, Cetin, Meliha, Gronert, Scott, Ma, Jingxiang, Erden, Ihsan
Format: Artikel
Sprache:eng
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Zusammenfassung:The pyrrolidine-catalyzed reactions of benzalacetones (I) with cyclopentadiene leads to isolable intermediate Michael adducts (III) and (IV), which are converted into 1,2-dihydropentalenes (V) at longer reaction times.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201533059