The Nugent Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry
The vast range of reactions mediated by titanocene monochloride (Cp2TiCl, the Nugent reagent) in organic synthetic chemistry is reviewed. The power of the Nugent reagent in organic chemistry is demonstrated by its ability to promote and/or catalyse several efficient transformations under mild reacti...
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| Veröffentlicht in: | European journal of organic chemistry 2015-07, Vol.2015 (21), p.4567-4591 |
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| container_issue | 21 |
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| container_title | European journal of organic chemistry |
| container_volume | 2015 |
| creator | Rosales, Antonio Rodríguez-García, Ignacio Muñoz-Bascón, Juan Roldan-Molina, Esther Padial, Natalia M. Morales, Laura Pozo García-Ocaña, Marta Oltra, J. Enrique |
| description | The vast range of reactions mediated by titanocene monochloride (Cp2TiCl, the Nugent reagent) in organic synthetic chemistry is reviewed. The power of the Nugent reagent in organic chemistry is demonstrated by its ability to promote and/or catalyse several efficient transformations under mild reaction conditions in the presence of several functional groups, in an environmentally friendly manner and with use of simple experimental procedures.
The different reactions promoted and/or catalysed by the Nugent reagent, a contemporary single‐electron transfer agent, are reported. The combination of radical intermediates and transition‐metal catalysis is an excellent tool for the development of new and efficient synthetic procedures. |
| doi_str_mv | 10.1002/ejoc.201500292 |
| format | Article |
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The different reactions promoted and/or catalysed by the Nugent reagent, a contemporary single‐electron transfer agent, are reported. The combination of radical intermediates and transition‐metal catalysis is an excellent tool for the development of new and efficient synthetic procedures.</description><subject>Metallocenes</subject><subject>Nugent reagent</subject><subject>Organometallic chemistry</subject><subject>Radical reactions</subject><subject>Titanium</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkM9LwzAUx4MoOKdXzwHPnUnapIm3UfZDHRuMibJLSNp062ybmXbo_nszKuLNw-P7Hnw_7_G-ANxiNMAIkXuzs-mAIEz9IMgZ6GEkRICYQOe-j8IowCJ8uwRXTbNDCAnGcA-sV1sD54eNqVu4NOqkD3AIx9ZVRaZ0aeDK2hIWNUxs3Zpqb51yR7hUWZGqEqo6gwu3UbWtTKvKskhhsjVV0bTueA0uclU25uZH--BlPFol02C2mDwmw1mQUoZJwHOq45jzKBY4zlDki3PNM010TimNCMfcqIwgTaJcpxgppKhmmMUMc8px2Ad33d69sx8H07RyZw-u9iclZoLxkApCvWvQuVJnm8aZXO5dUflfJEbylJ885Sd_8_OA6IDPojTHf9xy9LRI_rJBx_ogzNcvq9y7ZHEYU_k6n8iIzGcTsn6W0_AbbTuCHA</recordid><startdate>201507</startdate><enddate>201507</enddate><creator>Rosales, Antonio</creator><creator>Rodríguez-García, Ignacio</creator><creator>Muñoz-Bascón, Juan</creator><creator>Roldan-Molina, Esther</creator><creator>Padial, Natalia M.</creator><creator>Morales, Laura Pozo</creator><creator>García-Ocaña, Marta</creator><creator>Oltra, J. Enrique</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201507</creationdate><title>The Nugent Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry</title><author>Rosales, Antonio ; Rodríguez-García, Ignacio ; Muñoz-Bascón, Juan ; Roldan-Molina, Esther ; Padial, Natalia M. ; Morales, Laura Pozo ; García-Ocaña, Marta ; Oltra, J. Enrique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5612-8f5b778847917d047d088b8db2bf55542818ead20b24fbc10a0a5b61676185813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Metallocenes</topic><topic>Nugent reagent</topic><topic>Organometallic chemistry</topic><topic>Radical reactions</topic><topic>Titanium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rosales, Antonio</creatorcontrib><creatorcontrib>Rodríguez-García, Ignacio</creatorcontrib><creatorcontrib>Muñoz-Bascón, Juan</creatorcontrib><creatorcontrib>Roldan-Molina, Esther</creatorcontrib><creatorcontrib>Padial, Natalia M.</creatorcontrib><creatorcontrib>Morales, Laura Pozo</creatorcontrib><creatorcontrib>García-Ocaña, Marta</creatorcontrib><creatorcontrib>Oltra, J. Enrique</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rosales, Antonio</au><au>Rodríguez-García, Ignacio</au><au>Muñoz-Bascón, Juan</au><au>Roldan-Molina, Esther</au><au>Padial, Natalia M.</au><au>Morales, Laura Pozo</au><au>García-Ocaña, Marta</au><au>Oltra, J. Enrique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Nugent Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry</atitle><jtitle>European journal of organic chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2015-07</date><risdate>2015</risdate><volume>2015</volume><issue>21</issue><spage>4567</spage><epage>4591</epage><pages>4567-4591</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The vast range of reactions mediated by titanocene monochloride (Cp2TiCl, the Nugent reagent) in organic synthetic chemistry is reviewed. The power of the Nugent reagent in organic chemistry is demonstrated by its ability to promote and/or catalyse several efficient transformations under mild reaction conditions in the presence of several functional groups, in an environmentally friendly manner and with use of simple experimental procedures.
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Metallocenes Nugent reagent Organometallic chemistry Radical reactions Titanium |
| title | The Nugent Reagent: A Formidable Tool in Contemporary Radical and Organometallic Chemistry |
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