ChemInform Abstract: Asymmetric Aldol Reaction of Allenoates: Regulation for the Selective Formation of Isomeric Allenyl or Alkynyl Aldol Adduct

Allenoates (III) and threo‐3‐butynoates (V) are highly stereoselectively obtained by aldol reaction of allenoate with various aldehydes.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-08, Vol.46 (31), p.no-no
Hauptverfasser:	Bang, Jiyun, Kim, Hyuna, Kim, Jihyun, Yu, Chan-Mo
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions alkynes (acyclic compounds) allenes (acyclic compounds) diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism)
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Beschreibung
Zusammenfassung:	Allenoates (III) and threo‐3‐butynoates (V) are highly stereoselectively obtained by aldol reaction of allenoate with various aldehydes.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201531030