ChemInform Abstract: [gamma]-Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP

ChemInform Abstract: [gamma]-Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP

A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to [alpha]-glucosidase inhibitor homoDMDP.

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Veröffentlicht in:ChemInform 2015-07, Vol.46 (28)
Hauptverfasser: Jagadeesh, Y, Tran, A T, Luo, B, Auberger, N, Desire, J, Nakagawa, S, Kato, A, Zhang, Y, Sollogoub, M, Bleriot, Y
Format: Artikel
Sprache:eng
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Zusammenfassung:A short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to [alpha]-glucosidase inhibitor homoDMDP.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201528140