ChemInform Abstract: Bisoxazoline-Catalyzed Asymmetric Nucleophilic Addition of Diethyl Zinc to Fluorinated Alkyl Ketones: Enantiofacial Control by Changing the Bisoxazoline Substituent

Optimum reaction conditions (structure of catalyst, solvent) are studied for the bisoxazoline‐catalyzed asymmetric nucleophilic addition of diethyl zinc to fluorinated alkyl ketones.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-06, Vol.46 (24), p.no-no
Hauptverfasser:	Sasaki, Shigeru, Yamauchi, Takayasu, Kanai, Masatomi, Ishii, Akihiro, Higashiyama, Kimio
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols (benzene compounds) diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) halogen compounds (benzene compounds) halogenated alcohols organocatalysis Zinc
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Beschreibung
Zusammenfassung:	Optimum reaction conditions (structure of catalyst, solvent) are studied for the bisoxazoline‐catalyzed asymmetric nucleophilic addition of diethyl zinc to fluorinated alkyl ketones.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201524029