ChemInform Abstract: Gold(I)-Catalyzed Synthesis of Cyclic Sulfamidates: Current Scope, Stereochemistry and Competing Ene-Allene Cycloisomerization

The first gold‐catalyzed preparation of cyclic sulfamidates, leading to a range of unusually substituted and sterically hindered products under mild conditions is reported.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-05, Vol.46 (20), p.no-no
Hauptverfasser:	Higginbotham, Mari C. M., Kennedy, Lorna, Lindsay, Anita G., Troester, Andreas, Bebbington, Magnus W. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	annulation reactions catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) other 6-membered heterocycles (with 3 or more heteroatoms) phase-transfer catalysis ring closure reactions ring closure reactions, annulation reactions
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Beschreibung
Zusammenfassung:	The first gold‐catalyzed preparation of cyclic sulfamidates, leading to a range of unusually substituted and sterically hindered products under mild conditions is reported.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201520214