ChemInform Abstract: Synthesis of Bis-[alpha]-amino Acids Through Proline Catalyzed Asymmetric [alpha]-Amination of Higher Homologues of Garner's Aldehyde

ChemInform Abstract: Synthesis of Bis-[alpha]-amino Acids Through Proline Catalyzed Asymmetric [alpha]-Amination of Higher Homologues of Garner's Aldehyde

The convenient synthesis of bis-[alpha]-amino acid esters involves the proline catalyzed highly diastereoselective [alpha]-hydrazination of aldehydes (I) with dibenzyl azodicarboxylate as the key step.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2015-04, Vol.46 (17)
Hauptverfasser: Petakamsetty, Ramu, Das, Ram Pada, Ramapanicker, Ramesh
Format: Artikel
Sprache:eng
Schlagworte:
Amino acids
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Beschreibung
Zusammenfassung:The convenient synthesis of bis-[alpha]-amino acid esters involves the proline catalyzed highly diastereoselective [alpha]-hydrazination of aldehydes (I) with dibenzyl azodicarboxylate as the key step.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201517261