ChemInform Abstract: Cross-Metathesis/Isomerization/Allylboration Sequence for a Diastereoselective Synthesis of anti-Homoallylic Alcohols from Allylbenzene Derivatives and Aldehydes

A reaction sequence consisting of cross‐metathesis of allylarenes with vinylboronic acid, Ir‐catalyzed isomerization and allylboration to give homoallylic alcohols (IV) with excellent diastereoselectivity.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-04, Vol.46 (15), p.no-no
Hauptverfasser:	Hemelaere, Remy, Carreaux, Francois, Carboni, Bertrand
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols (benzene compounds) C-C bond formation catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) phase-transfer catalysis
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Beschreibung
Zusammenfassung:	A reaction sequence consisting of cross‐metathesis of allylarenes with vinylboronic acid, Ir‐catalyzed isomerization and allylboration to give homoallylic alcohols (IV) with excellent diastereoselectivity.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201515095