ChemInform Abstract: Palladium-Catalyzed Chemoselective Allylic Substitution, Suzuki-Miyaura Cross-Coupling, and Allene Formation of Bifunctional 2-B(pin)-Substituted Allylic Acetate Derivatives
The allylic substitution of 2‐pinacolborane‐substituted allylic acetates (I) with nucleophiles (II) leads to boranes (III), which can be converted without isolation into ketones (IV) and trisubstituted alkenes (VI).
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| Veröffentlicht in: | ChemInform 2015-03, Vol.46 (10), p.no-no |
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| creator | Kim, Byeong-Seon Hussain, Mahmud M. Hussain, Nusrah Walsh, Patrick J. |
| description | The allylic substitution of 2‐pinacolborane‐substituted allylic acetates (I) with nucleophiles (II) leads to boranes (III), which can be converted without isolation into ketones (IV) and trisubstituted alkenes (VI). |
| doi_str_mv | 10.1002/chin.201510054 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | allenes (benzene compounds) amination amination, N‐alkylation, N‐arylation C-C bond formation chemoselective reactions N-alkylation N-arylation organo-boron compounds |
| title | ChemInform Abstract: Palladium-Catalyzed Chemoselective Allylic Substitution, Suzuki-Miyaura Cross-Coupling, and Allene Formation of Bifunctional 2-B(pin)-Substituted Allylic Acetate Derivatives |
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