ChemInform Abstract: Palladium-Catalyzed Chemoselective Allylic Substitution, Suzuki-Miyaura Cross-Coupling, and Allene Formation of Bifunctional 2-B(pin)-Substituted Allylic Acetate Derivatives

ChemInform Abstract: Palladium-Catalyzed Chemoselective Allylic Substitution, Suzuki-Miyaura Cross-Coupling, and Allene Formation of Bifunctional 2-B(pin)-Substituted Allylic Acetate Derivatives

The allylic substitution of 2‐pinacolborane‐substituted allylic acetates (I) with nucleophiles (II) leads to boranes (III), which can be converted without isolation into ketones (IV) and trisubstituted alkenes (VI).

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Veröffentlicht in:ChemInform 2015-03, Vol.46 (10), p.no-no
Hauptverfasser: Kim, Byeong-Seon, Hussain, Mahmud M., Hussain, Nusrah, Walsh, Patrick J.
Format: Artikel
Sprache:eng
Schlagworte:
allenes (benzene compounds)
amination
amination, N‐alkylation, N‐arylation
C-C bond formation
chemoselective reactions
N-alkylation
N-arylation
organo-boron compounds
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Zusammenfassung:The allylic substitution of 2‐pinacolborane‐substituted allylic acetates (I) with nucleophiles (II) leads to boranes (III), which can be converted without isolation into ketones (IV) and trisubstituted alkenes (VI).
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201510054