ChemInform Abstract: Rhodium-Catalyzed Alkene Hydrosilylation via a Hydride Shuttle Process by Diene Ligands: Dramatic Enhancement of Regio- and Diastereoselectivity
The precursors oxasilacyclopentanes for trans‐1,3‐diols are synthesized in a highly regio‐ and diastereoselective manner by using [RhCl(BINAP)]2 as catalyst.
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| Veröffentlicht in: | ChemInform 2015-03, Vol.46 (10), p.no-no |
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| container_title | ChemInform |
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| creator | Hua, Yuanda Nguyen, Hiep H. Trog, Gabriela Berlin, Adam S. Jeon, Junha |
| description | The precursors oxasilacyclopentanes for trans‐1,3‐diols are synthesized in a highly regio‐ and diastereoselective manner by using [RhCl(BINAP)]2 as catalyst. |
| doi_str_mv | 10.1002/chin.201510085 |
| format | Article |
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| ispartof | ChemInform, 2015-03, Vol.46 (10), p.no-no |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alcohols (acyclic compounds) alcohols (benzene compounds) catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) hydrosilylation hydrosilylation, silylation, phosphorylation phase-transfer catalysis phosphorylation ring opening reactions silylation |
| title | ChemInform Abstract: Rhodium-Catalyzed Alkene Hydrosilylation via a Hydride Shuttle Process by Diene Ligands: Dramatic Enhancement of Regio- and Diastereoselectivity |
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