ChemInform Abstract: Rhodium-Catalyzed Alkene Hydrosilylation via a Hydride Shuttle Process by Diene Ligands: Dramatic Enhancement of Regio- and Diastereoselectivity

The precursors oxasilacyclopentanes for trans‐1,3‐diols are synthesized in a highly regio‐ and diastereoselective manner by using [RhCl(BINAP)]2 as catalyst.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-03, Vol.46 (10), p.no-no
Hauptverfasser:	Hua, Yuanda, Nguyen, Hiep H., Trog, Gabriela, Berlin, Adam S., Jeon, Junha
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols (acyclic compounds) alcohols (benzene compounds) catalysis catalysis, phase‐transfer catalysis diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) hydrosilylation hydrosilylation, silylation, phosphorylation phase-transfer catalysis phosphorylation ring opening reactions silylation
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The precursors oxasilacyclopentanes for trans‐1,3‐diols are synthesized in a highly regio‐ and diastereoselective manner by using [RhCl(BINAP)]2 as catalyst.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201510085