ChemInform Abstract: Transition-Metal-Free Tandem Oxidative Removal of Benzylic Methylene Group by C-C and C-N Bond Cleavage Followed by Intramolecular New Aryl C-N Bond Formation under Radical Conditions

ChemInform Abstract: Transition-Metal-Free Tandem Oxidative Removal of Benzylic Methylene Group by C-C and C-N Bond Cleavage Followed by Intramolecular New Aryl C-N Bond Formation under Radical Conditions

The novel tandem oxidative transformation of dibenzodiazepines to phenazines proceeds under transition‐metal‐free and mild conditions in the presence of K2S2O8 or DDQ as the oxidizing agent.

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Veröffentlicht in:ChemInform 2015-03, Vol.46 (10), p.no-no
Hauptverfasser: Laha, Joydev K., Tummalapalli, K. S. Satyanarayana, Gupta, Ankur
Format: Artikel
Sprache:eng
Schlagworte:
pyrazine derivatives
ring contraction
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Zusammenfassung:The novel tandem oxidative transformation of dibenzodiazepines to phenazines proceeds under transition‐metal‐free and mild conditions in the presence of K2S2O8 or DDQ as the oxidizing agent.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201510226