Synthesis and Characterization of Secondary Nitrosamines from Secondary Amines Using Sodium Nitrite and p-Toluenesulfonic Acid

Synthesis and Characterization of Secondary Nitrosamines from Secondary Amines Using Sodium Nitrite and p-Toluenesulfonic Acid

We synthesized nitrosamines (R2NNO) with R=iPr (1), nPr (2), nBu (3), and hydroxyethyl (4) from the amine using sodium nitrite/p‐toluenesulfonic acid in CH2Cl2. The rate of formation of 1–4 increases in the direction iPr

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Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2015-03, Vol.10 (3), p.674-678
Hauptverfasser: Miró Sabaté, Carles, Delalu, Henri
Format: Artikel
Sprache:eng
Schlagworte:
amines
Chemistry
energetic materials
hydrazines
NMR
Nuclear magnetic resonance
sodium
synthetic methods
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Zusammenfassung:We synthesized nitrosamines (R2NNO) with R=iPr (1), nPr (2), nBu (3), and hydroxyethyl (4) from the amine using sodium nitrite/p‐toluenesulfonic acid in CH2Cl2. The rate of formation of 1–4 increases in the direction iPr
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201403182