Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission
A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the...
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Veröffentlicht in: | Small (Weinheim an der Bergstrasse, Germany) Germany), 2015-02, Vol.11 (7), p.792-796 |
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creator | Kunz, Daniel A. Leitl, Markus J. Schade, Lukas Schmid, Jasmin Bojer, Beate Schwarz, Ulrich T. Ozin, Geoffrey A. Yersin, Hartmut Breu, Josef |
description | A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi‐epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers. |
doi_str_mv | 10.1002/smll.201400826 |
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Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi‐epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers.</description><subject>[Ru(bpy)3]2</subject><subject>clay nanoplatelets</subject><subject>confinement</subject><subject>host-guest structures</subject><subject>Nanotechnology</subject><subject>polarized emission</subject><issn>1613-6810</issn><issn>1613-6829</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEQQBdRUKtXzwEvimzNx34kRym1CrVq1YqKhOzuLKammzXZouuvt6VSvHmaObw3Ay8IDgjuEozpqZ8Z06WYRBhzmmwEOyQhLEw4FZvrneDtYNf7KcaM0CjdCeB2rrwOodaN-tLKoIGzn80bsiV6Gc-Psro9Zq_0BGUt6tmq1BXMoGqQrlDPqBaNVGVroxow0Hj0pMEUHt1Yo5z-hgL1Z9p7bau9YKtUxsP-7-wED-f9-95FOLweXPbOhmFOMU5CWnAOlEVZinPBRZQDJxHwOGe8hKjkhKYFJknG85TGjGV5VMQiFzFJqCq4iFknOFzdrZ39mINv5NTOXbV4KUkSR4LFguAF1V1RubPeOyhl7fRMuVYSLJcp5TKlXKdcCGIlfGoD7T-0vLsaDv-64crVvoGvtavcu0xSlsbycTSQjD5PxuNHIifsByRghpE</recordid><startdate>20150201</startdate><enddate>20150201</enddate><creator>Kunz, Daniel A.</creator><creator>Leitl, Markus J.</creator><creator>Schade, Lukas</creator><creator>Schmid, Jasmin</creator><creator>Bojer, Beate</creator><creator>Schwarz, Ulrich T.</creator><creator>Ozin, Geoffrey A.</creator><creator>Yersin, Hartmut</creator><creator>Breu, Josef</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20150201</creationdate><title>Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission</title><author>Kunz, Daniel A. ; Leitl, Markus J. ; Schade, Lukas ; Schmid, Jasmin ; Bojer, Beate ; Schwarz, Ulrich T. ; Ozin, Geoffrey A. ; Yersin, Hartmut ; Breu, Josef</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2006-2d88e234b70c9894ce814e85c38fe4f8127d016b8c72533bc4d59c95162ad8953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>[Ru(bpy)3]2</topic><topic>clay nanoplatelets</topic><topic>confinement</topic><topic>host-guest structures</topic><topic>Nanotechnology</topic><topic>polarized emission</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kunz, Daniel A.</creatorcontrib><creatorcontrib>Leitl, Markus J.</creatorcontrib><creatorcontrib>Schade, Lukas</creatorcontrib><creatorcontrib>Schmid, Jasmin</creatorcontrib><creatorcontrib>Bojer, Beate</creatorcontrib><creatorcontrib>Schwarz, Ulrich T.</creatorcontrib><creatorcontrib>Ozin, Geoffrey A.</creatorcontrib><creatorcontrib>Yersin, Hartmut</creatorcontrib><creatorcontrib>Breu, Josef</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kunz, Daniel A.</au><au>Leitl, Markus J.</au><au>Schade, Lukas</au><au>Schmid, Jasmin</au><au>Bojer, Beate</au><au>Schwarz, Ulrich T.</au><au>Ozin, Geoffrey A.</au><au>Yersin, Hartmut</au><au>Breu, Josef</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission</atitle><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle><addtitle>Small</addtitle><date>2015-02-01</date><risdate>2015</risdate><volume>11</volume><issue>7</issue><spage>792</spage><epage>796</epage><pages>792-796</pages><issn>1613-6810</issn><eissn>1613-6829</eissn><abstract>A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi‐epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers.</abstract><cop>Weinheim</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1002/smll.201400826</doi><tpages>5</tpages></addata></record> |
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subjects | [Ru(bpy)3]2 clay nanoplatelets confinement host-guest structures Nanotechnology polarized emission |
title | Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission |
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