Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission

A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2015-02, Vol.11 (7), p.792-796
Hauptverfasser: Kunz, Daniel A., Leitl, Markus J., Schade, Lukas, Schmid, Jasmin, Bojer, Beate, Schwarz, Ulrich T., Ozin, Geoffrey A., Yersin, Hartmut, Breu, Josef
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container_issue 7
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container_title Small (Weinheim an der Bergstrasse, Germany)
container_volume 11
creator Kunz, Daniel A.
Leitl, Markus J.
Schade, Lukas
Schmid, Jasmin
Bojer, Beate
Schwarz, Ulrich T.
Ozin, Geoffrey A.
Yersin, Hartmut
Breu, Josef
description A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi‐epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers.
doi_str_mv 10.1002/smll.201400826
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subjects [Ru(bpy)3]2
clay nanoplatelets
confinement
host-guest structures
Nanotechnology
polarized emission
title Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission
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