Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission

Quasi-epitaxial Growth of [Ru(bpy)3]2+ by Confinement in Clay Nanoplatelets Yields Polarized Emission

A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2015-02, Vol.11 (7), p.792-796
Hauptverfasser: Kunz, Daniel A., Leitl, Markus J., Schade, Lukas, Schmid, Jasmin, Bojer, Beate, Schwarz, Ulrich T., Ozin, Geoffrey A., Yersin, Hartmut, Breu, Josef
Format: Artikel
Sprache:eng
Schlagworte:
[Ru(bpy)3]2
clay nanoplatelets
confinement
host-guest structures
Nanotechnology
polarized emission
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A nano confinement strategy is presented to control the spatial orientation and emission polarization of phosphorescent metal complexes. Through nano‐confinement of the phosphorescent metal complex [Ru(bpy)3]2+ by attaching it to anionic clay nanoplatelets, it is possible to simultaneously lock the spatial orientation of the complex and fix its emission polarization. This quasi‐epitaxial approach may provide a future work strategy directed at light emitting diodes and lasers.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.201400826