ChemInform Abstract: Hetero-Diels-Alder Reaction of Phosphorylated Nitroso Alkenes with Enol Ethers on Water: A Clean Approach Toward 1,2-Oxazine Derivatives

ChemInform Abstract: Hetero-Diels-Alder Reaction of Phosphorylated Nitroso Alkenes with Enol Ethers on Water: A Clean Approach Toward 1,2-Oxazine Derivatives

The direct construction of 5,6‐dihydro‐4H‐1,2‐oxazines is achieved through hetero‐Diels—Alder reaction of enol ethers with nitroso alkenes, generated is situ by dehydrohalogenation of oximes bearing an electron withdrawing substituent.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2015-02, Vol.46 (7), p.no-no
Hauptverfasser: de los Santos, Jesus M., Ignacio, Roberto, Es Sbai, Zouhair, Aparicio, Domitila, Palacios, Francisco
Format: Artikel
Sprache:eng
Schlagworte:
cycloaddition reactions
organo-phosphorus compounds
oxazine derivatives
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Zusammenfassung:The direct construction of 5,6‐dihydro‐4H‐1,2‐oxazines is achieved through hetero‐Diels—Alder reaction of enol ethers with nitroso alkenes, generated is situ by dehydrohalogenation of oximes bearing an electron withdrawing substituent.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201507257