ChemInform Abstract: Silyl Triflate-Accelerated Additions of Catalytically Generated Zinc Acetylides to N-Phenyl Nitrones

After deprotection with TosOH in MeOH the free N‐hydroxyl propargylamines are obtained, whereas the Tms‐protected products (VI) are isolated due to decomposition of the products during the removal of the Tms group, in some cases.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2015-02, Vol.46 (6), p.no-no
Hauptverfasser:	Downey, C. Wade, Maxwell, Erin N., Confair, Danielle N.
Format:	Artikel
Sprache:	eng
Schlagworte:	amines (benzene compounds) C-C bond formation catalysis catalysis, phase‐transfer catalysis organo-silicon compounds phase-transfer catalysis Zinc
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	After deprotection with TosOH in MeOH the free N‐hydroxyl propargylamines are obtained, whereas the Tms‐protected products (VI) are isolated due to decomposition of the products during the removal of the Tms group, in some cases.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201506076