ChemInform Abstract: Solvent-Free Synthesis of a Secondary N-Benzhydrylamine as a Chiral Reagent for Asymmetric Deprotonation of Bicyclic N-Benzylamino Ketones

ChemInform Abstract: Solvent-Free Synthesis of a Secondary N-Benzhydrylamine as a Chiral Reagent for Asymmetric Deprotonation of Bicyclic N-Benzylamino Ketones

(R)‐N‐benzhydryl‐1‐phenylethylamine is utilized as chiral auxiliary in asymmetric deprotonations of N‐benzyl analogues of tropinone and granatanone.

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Veröffentlicht in:ChemInform 2014-12, Vol.45 (49), p.no-no
Hauptverfasser: Nodzewska, Aneta, Sidorowicz, Katarzyna, Sienkiewicz, Michal
Format: Artikel
Sprache:eng
Schlagworte:
addition reactions
C-C bond formation
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
pyridine derivatives with bridges
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Beschreibung
Zusammenfassung:(R)‐N‐benzhydryl‐1‐phenylethylamine is utilized as chiral auxiliary in asymmetric deprotonations of N‐benzyl analogues of tropinone and granatanone.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201449025