ChemInform Abstract: The Efficient Method for the Preparation of Alkenylsilanes from Organoaluminums

The reaction of alkynes with trimethylaluminum or iBu2AlH gives 1‐alkenylaluminum intermediates which are readily trapped by sulfonic acid silyl esters to produce vinyl silanes in good yields.

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Veröffentlicht in:	ChemInform 2014-11, Vol.45 (47), p.no-no
Hauptverfasser:	Kadikova, Rita N., Zosim, Tat'yana P., Dzhemilev, Usein M., Ramazanov, Ilfir R.
Format:	Artikel
Sprache:	eng
Schlagworte:	organo-silicon compounds reactions of organo-metal compounds
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description	The reaction of alkynes with trimethylaluminum or iBu2AlH gives 1‐alkenylaluminum intermediates which are readily trapped by sulfonic acid silyl esters to produce vinyl silanes in good yields.
doi_str_mv	10.1002/chin.201447209
format	Article
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source	Wiley Online Library Journals Frontfile Complete
subjects	organo-silicon compounds reactions of organo-metal compounds
title	ChemInform Abstract: The Efficient Method for the Preparation of Alkenylsilanes from Organoaluminums
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