Control of Solid-state Circularly Polarized Luminescence of Binaphthyl Organic Fluorophores through Environmental Changes

The signs of solid‐state circularly polarized luminescence (CPL) of axially chiral binaphthyl organic fluorophores were successfully controlled by changing the environment of their solid‐state matrices from a poly(methyl methacrylate) (PMMA) film‐dispersed state to a KBr pellet‐dispersed state. I sa...

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Veröffentlicht in:Asian journal of organic chemistry 2013-05, Vol.2 (5), p.404-410
Hauptverfasser: Kimoto, Takaya, Amako, Tomoyuki, Tajima, Nobuo, Kuroda, Reiko, Fujiki, Michiya, Imai, Yoshitane
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container_end_page 410
container_issue 5
container_start_page 404
container_title Asian journal of organic chemistry
container_volume 2
creator Kimoto, Takaya
Amako, Tomoyuki
Tajima, Nobuo
Kuroda, Reiko
Fujiki, Michiya
Imai, Yoshitane
description The signs of solid‐state circularly polarized luminescence (CPL) of axially chiral binaphthyl organic fluorophores were successfully controlled by changing the environment of their solid‐state matrices from a poly(methyl methacrylate) (PMMA) film‐dispersed state to a KBr pellet‐dispersed state. I saw the sign: The signs of solid‐state circularly polarized luminescence (CPL) of axially chiral binaphthyl organic fluorophores can be controlled by changing the environment. Switching the solid‐state matrices from a poly(methyl methacrylate) (PMMA) film‐dispersed state to a KBr pellet‐dispersed state reverses the CPL sign.
doi_str_mv 10.1002/ajoc.201300034
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source Wiley Online Library Journals Frontfile Complete
subjects binaphthyls
chirality
circular dichroism
circularly polarized luminescence
fluorescence
Organic chemistry
title Control of Solid-state Circularly Polarized Luminescence of Binaphthyl Organic Fluorophores through Environmental Changes
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