Synthesis of some novel quinone diimine derivatives of benzo-15-crown-5 for application in Hg2+ recognition

ABSTRACT A series of novel fluoroionophore bearing derivatives of benzo‐15‐crown‐5 were synthesized by the amination of benzo‐15‐crown‐5 followed by condensation with different quinones in the presence of titanium tetrachloride (TiCl4) and 1,4‐diazabicyclo‐[2.2.2]octane. The compounds were character...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Luminescence (Chichester, England) England), 2014-09, Vol.29 (6), p.586-590
Hauptverfasser:	Jagadale, S. D., Sawant, A. D., Patil, P. P., Patil, D. R., Mulik, A. G., Chandam, D. R., Sankpal, S. A., Deshmukh, M. B.
Format:	Artikel
Sprache:	eng
Schlagworte:	4-Aminobenzo-15-crown-5 (4AB15C5) benzo-15-crown-5 (B15C5) emission spectroscopy metal ion sensor quinone diimine derivatives
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	ABSTRACT A series of novel fluoroionophore bearing derivatives of benzo‐15‐crown‐5 were synthesized by the amination of benzo‐15‐crown‐5 followed by condensation with different quinones in the presence of titanium tetrachloride (TiCl4) and 1,4‐diazabicyclo‐[2.2.2]octane. The compounds were characterized by infrared, 1H and 13C nuclear magnetic resonance, mass spectroscopy and elemental analysis. Absorption and fluorescence spectral characteristics of these compounds were studied. It was observed that the anthraquinone derivative was acting as an Hg2+ ion sensor. Copyright © 2013 John Wiley & Sons, Ltd.
ISSN:	1522-7235 1522-7243
DOI:	10.1002/bio.2585