Expedient Synthesis of Novel Ferrocenyl Spiropyrrolidines Through 1,3-Dipolar Cycloaddition Reaction
The synthesis of novel ferrocenyl spiropyrrolidines through the cycloaddition of azomethine ylides generated by a decarboxylative route from sarcosine and diketones with the dipolarophile, Knoevenagel adduct of ferrocene carbaldehyde is described. The regiochemistry and stereochemistry of the cycloa...
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| Veröffentlicht in: | Journal of heterocyclic chemistry 2014-07, Vol.51 (4), p.906-910 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis of novel ferrocenyl spiropyrrolidines through the cycloaddition of azomethine ylides generated by a decarboxylative route from sarcosine and diketones with the dipolarophile, Knoevenagel adduct of ferrocene carbaldehyde is described. The regiochemistry and stereochemistry of the cycloadducts were confirmed by X‐ray analysis of one of the synthesized cycloadducts. |
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| ISSN: | 0022-152X 1943-5193 |
| DOI: | 10.1002/jhet.1731 |