ChemInform Abstract: [1,5]-Anion Relay via Intramolecular Proton Transfer to Generate 3,3-Bis(silyl) Allyloxy Lithium: A Useful Scaffold for Syn-Addition to Aldehydes and Ketones

ChemInform Abstract: [1,5]-Anion Relay via Intramolecular Proton Transfer to Generate 3,3-Bis(silyl) Allyloxy Lithium: A Useful Scaffold for Syn-Addition to Aldehydes and Ketones

The reaction proceeds via [1,5]‐anion relay in 3,3‐bis(silyl) benzyl enol ether.

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Veröffentlicht in:ChemInform 2014-08, Vol.45 (32), p.no-no
Hauptverfasser: Lin, Xinglong, Ye, Xincui, Sun, Xianwei, Zhang, Yuebao, Gao, Lu, Song, Zhenlei
Format: Artikel
Sprache:eng
Schlagworte:
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
organo-silicon compounds
Protons
reactions of organo-metal compounds
rearrangements
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Zusammenfassung:The reaction proceeds via [1,5]‐anion relay in 3,3‐bis(silyl) benzyl enol ether.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201432198