ChemInform Abstract: Selective Hydrosilation of CO2 to a Bis(silylacetal) Using an Anilido Bipyridyl-Ligated Organoscandium Catalyst
Mechanistic experiments suggest that the sequestration of free tris(pentafluorophenyl)borane by the hemilabile carboxylate contributes to the selectivity observed and prevents over reduction to methane.
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| Veröffentlicht in: | ChemInform 2014-07, Vol.45 (30), p.no-no |
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| creator | LeBlanc, Francis A. Piers, Warren E. Parvez, Masood |
| description | Mechanistic experiments suggest that the sequestration of free tris(pentafluorophenyl)borane by the hemilabile carboxylate contributes to the selectivity observed and prevents over reduction to methane. |
| doi_str_mv | 10.1002/chin.201430186 |
| format | Article |
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| ispartof | ChemInform, 2014-07, Vol.45 (30), p.no-no |
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| language | eng |
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| source | Wiley Online Library All Journals |
| subjects | catalysis catalysis, phase‐transfer catalysis hydrogenation organo-silicon compounds phase-transfer catalysis reduction reduction, hydrogenation |
| title | ChemInform Abstract: Selective Hydrosilation of CO2 to a Bis(silylacetal) Using an Anilido Bipyridyl-Ligated Organoscandium Catalyst |
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