ChemInform Abstract: Selective Hydrosilation of CO2 to a Bis(silylacetal) Using an Anilido Bipyridyl-Ligated Organoscandium Catalyst

Mechanistic experiments suggest that the sequestration of free tris(pentafluorophenyl)borane by the hemilabile carboxylate contributes to the selectivity observed and prevents over reduction to methane.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2014-07, Vol.45 (30), p.no-no
Hauptverfasser:	LeBlanc, Francis A., Piers, Warren E., Parvez, Masood
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis catalysis, phase‐transfer catalysis hydrogenation organo-silicon compounds phase-transfer catalysis reduction reduction, hydrogenation
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Mechanistic experiments suggest that the sequestration of free tris(pentafluorophenyl)borane by the hemilabile carboxylate contributes to the selectivity observed and prevents over reduction to methane.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201430186