ChemInform Abstract: Asymmetric Homoenolate Additions to Acyl Phosphonates Through Rational Design of a Tailored N-Heterocyclic Carbene Catalyst

A highly selective NHC‐catalyzed synthesis of γ‐butyrolactones from the fusion of enals and α‐ketophosphonates is reported.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2014-07, Vol.45 (30), p.no-no
Hauptverfasser:	Jang, Ki Po, Hutson, Gerri E., Johnston, Ryne C., McCusker, Elizabeth O., Cheong, Paul H.-Y., Scheidt, Karl A.
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) furan derivatives organo-phosphorus compounds ring opening reactions
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Beschreibung
Zusammenfassung:	A highly selective NHC‐catalyzed synthesis of γ‐butyrolactones from the fusion of enals and α‐ketophosphonates is reported.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201430190